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  鋁電池具有理論容量高，安全性好、成本低等優點，是新一代儲能技術的代表。設計和開發高比能、綠色可持續正極電極材料是構建高性能鋁離子電池的關鍵。氮氧自由基（TEMPO）聚合物作為典型有機正極材料已被廣泛應用于鋰離子電池、鈉離子電池、鋅離子電池等電池體系，并表現出高電壓、高功率、綠色可再生特性。然而，由于多數氮氧自由基在路易斯酸有機電解液中電化學氧化還原不可逆，使其無法應用于鋁離子電池正極材料。例如，在酸性Al(OTf)₃乙腈電解液中，TEMPO歧化成TEMPO⁺與 TEMPO^-，而后者與Al(OTf)₃配位形成穩定的[Al(OTf)₃TEMPO]^-絡合物，其較高的氧化電位導致TEMPO電化學氧化還原不可逆而無法應用于鋁電正極。

  論文鏈接：https://doi.org/10.1021/jacs.3c04203

作者簡介

張凱

2018年于澳大利亞昆士蘭大學獲理學博士學位；2018-2020年在美國約翰霍普金斯大學開展博士后研究。2020年加入浙江理工大學化學與化工學院，任特聘副教授。主要研究領域為能源和高分子化學，研究興趣包括鋁離子電池、聚合物基柔性電池、有機水系液流電池等的機理研究和結構設計。以通訊作者/第一作者身份在J. Am. Chem. Soc., ACS Energy Lett., Energy Storage Mater., J. Mater. Chem. A, Chem. Eng. J.等學術刊物上發表論文十余篇，受到了國內外學術界的廣泛關注。

Zhongfan Jia（賈中凡）

Zhongfan Jia is an Associate Professor of Chemistry at Flinders University, Australia. He graduated from Fudan University with a PhD in Polymer Chemistry and Physics in 2007, followed by a postdoctoral position in the Centre for Advanced Macromolecular Design (CAMD) at the University of New South Wales. From 2009 to 2020, he was a senior research fellow at the Australian Institute for Bioengineering and Nanotechnology (AIBN), the University of Queensland. He is a recipient of the Australian Research Council Future Fellow and Advanced Queensland Industry Fellow. In 2019, he was appointed as a Lecturer in Chemistry at the University of New England. He joined Flinders University as a Senior Lecturer in 2020 and was promoted to Associate Professor in 2022. His research interests include polymer chemistry, organic electrochemistry, biomaterial, catalysis, and energy storage.

Michelle L. Coote

Professor Michelle Coote is a Georgina Sweet ARC Laureate Fellow and is also an Executive Editor of the Journal of the American Chemical Society. She graduated with a PhD from the University of New South Wales. She established her own research group at the ANU in 2004, where she was promoted to Professor in 2011. She moved to Flinders University as a Matthew Flinders Professor in Chemistry in 2022. She is a member of the new ARC Centre of Excellence for Quantum Biotechnology. Professor Coote is an elected fellow of the Australian Academy of Science (FAA), the Royal Australian Chemical Institute (FRACI) and the Royal Society of Chemistry (FRSC). She has received many awards including the recent HG Smith Medal (2016), the RSC Australasian Lectureship (2020) and Leighton Medal (2021) Her current research spans theoretical and experimental chemistry, in areas as diverse as polymer chemistry, organic synthesis, physical chemistry and organometallic catalysis.