One-pot synthesis of ternary alloy CuFePtnanoparticles anchored on reduced graphene oxide and their enhancedelectrocatalytic activity for both methanol and formic acid oxidation reactions.
作者：?Xuan Zhang*, Bei Zhang, Dong-Yue Liu, Jin-LiQiao.
關(guān)鍵字：Ternary alloy CuFePt nanocatalysts, Reduced graphene oxide, Methanol oxidation reaction, Formic acid oxidation reaction, Fuel cells
論文來源：期刊
具體來源：Electrochim. Acta, 2015, 177, 93–99.
發(fā)表時間：2015年
By combining alloying and supporting approaches, ternary alloy CuFePt nanocatalysts anchored on the reduced graphene oxide (RGO) have been facilely synthesized by using NaBH4 as reductant in an ambient one-pot strategy. The as-prepared CuFePt/RGO hybrids were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), energy-dispersive spectrometry (EDS), and transmission electron microscopy (TEM). The electrochemical measurements showed that the ternary CuFePt/RGO exhibited a highly enhanced electrocatalytic activity and improved stability for the methanol oxidation reaction (MOR) and formic acid oxidation reaction (FAOR), much superior to those of binary CuPt/RGO and FePt/RGO, and mono-metallic Pt/RGO counterparts. The atomic composition ratios of Cu and Fe in CuFePt/RGO were also optimized to probe their influences on electrocatalytic performance. The straightforward synthesis of ternary CuFePt/RGO provides a promising strategy for development of high performancePt alloy catalysts for both MOR and FAOR in fuel cells.