Influence of attapulgites on cure-reaction-induced phase separation in epoxy/poly(ether sulfone) blends
作者：Zhao, L.; Zhan, G. Z.; Yu, Y. F.; Tang, X. L.; Li, S. J.,
關鍵字：thermoplastics, thermoset, phase separation
論文來源：期刊
具體來源：Journal of Applied Polymer Science 2008, 108, (2), 953-959
發表時間：2008年
The influence of attapulgites (ATTs) on cure-reaction-induced phase separation in diglycidyl ether of bisphenol A/poly(ether sulfone) (PES) blends has been studied with scanning electron microscopy (SEM), transmission electron microscopy (TEM), optical microscopy, time-resolved light scattering, and dynamic mechanical analysis at different ATT and PES concentrations. The SEM results show that the incorporation of a small amount of ATT into the blends can change the final phase morphology markedly and affect the secondary phase separation. The TEM results show that ATT particles are pinned down by the interfacial tension at the phase interfaces, and this slows the interfacial motion. In addition, the incorporation of a small amount of ATT particles can improve the modulus because of the increased interfacial interaction of the PES-rich and epoxy-rich phases.