Facile Synthesis of Monodisperse Polymer/SiO2/Polymer/TiO2/ Tetra-layer Hybrid Microspheres and the Corresponding Double-Walled Hollow SiO2/TiO2 Microspheres
作者：Han Zhang, Xu Zhang, Xinlin Yang*
關(guān)鍵字：Photocatalyst, Double-walled hollow microspheres,
論文來源：期刊
具體來源：J. Colloid Interface Sci., 348 (2), 431-440 (2010). DOI: 10.1016/j.jcis.2010.04-059
發(fā)表時間：2010年
Monodisperse tetra-layer poly(ethyleneglycol dimethacrylate-co-methacrylic acid) (P(EGDMA-co-MAA))/SiO2/P(EGDMA-co-MAA)/TiO2 tetra-layer microspheres were facilely synthesized by the combination of the distillation precipitation polymerization for the preparation of P(EGDMA-co-MAA) layers and the controlled sol–gel hydrolysis of inorganic precursors for the formation of silica (SiO2) and titania (TiO2) layers. The thickness of the outer titania shell-layer was well-controlled via altering the feed of titanium tetrabutoxide (TBOT) during the sol–gel hydrolysis, while the size of polymeric layers were facilely controlled via a multi-step addition of ethyleneglycol dimethacrylate (EGDMA) crosslinker and methacrylic acid (MAA) monomer during the polymerization. The corresponding double-walled hollow inorganic microspheres containing SiO2 inner shell and TiO2 outer shell with various thickness were obtained after the selective removal of P(EGDMA-co-MAA) components via the calcination of the tetra-layer polymer/SiO2/polymer/TiO2 microspheres under 550 C for 4 h in air. The structure and morphology of the resultant
microspheres were characterized by transmission electron microscopy (TEM), X-ray diffractometer (XRD), X-ray photoelectron microscopy (XPS), and thermogravimetric analysis (TGA). Further, the photocatalytic properties of the resultant double-walled hollow SiO2/TiO2 microspheres were studied by photocatalytic degradation of methyl orange (MO) with ultraviolet (UV) irradiation of a 500Whigh-pressure mercury lamp.