(Angew. Chem. Int. Ed.) Cucurbit[8]uril Mediated Supramolecular Heterodimerisation and Photoinduced [2+2] Heterocycloaddition to Generate Unexpected [2]Rotaxanes
作者：Zhang, S.; Zhang, L.; Chen, A.; An, Y.; Chen, X.*; Yang, H.*; Li, Q.*
關鍵字：Rotaxane
論文來源：期刊
具體來源：Angewandte Chemie International Edition, 2024, 63, e202410130.
發表時間：2024年
In contrast to the self-assembly of homosupramolecules, the self-assembly of heterosupramolecules is more challenging and significant in various fields. Herein, we design and investigate a cucurbit[8]uril-mediated heterodimerisation based on an arene-fluoroarene strategy. Furthermore, the heteroternary complex is found to be able to undergo a photoinduced [2+2] heterocycloaddition, resulting in the formation of an unexpected [2]rotaxane. This work demonstrates a novel supramolecular heterodimerisation system, not only contributing to the development of photoisomerisation systems, but also enriching synthetic methodologies of mechanically interlocked molecules.