Regio-selective synthesis of polyepichlorohydrin diol using Zn–Co(III) double metal cyanide complex
作者：Ren-Jian Wei, Ying-Ying Zhang, Xing-Hong Zhang,* Bin-Yang Du and Zhi-Qiang Fan
關鍵字：Epichlorohydrin,Ring-opening polymerization, Zn–Co(III) double metal cyanide complex
論文來源：期刊
具體來源：RSC Adv., 2014, 4, 21765–21771
發表時間：2014年
A simple one-pot ring-opening polymerization (ROP) of epichlorohydrin (ECH) was successfully performed by a heterogeneous Zn–Co(III) double metal cyanide complex (Zn–Co(III) DMCC) catalyst, affording regioregular poly(ECH) diol with a head-to-tail content of >99% in the absence of organic solvent and/or protic compound. No cyclic or oligomer by-product was observed, and the employed Zn–Co(III) DMCC catalyst was recyclable. ROP of (R)- or (S)-ECH led to the generation of semi-crystalline poly(ECH) diol with a melting point of 81 C or 102 C, respectively. These regio-regular poly(ECH)s with two end hydroxyl groups are versatile platforms for ECH-based functionalized polymers.
