89. A Click Chemistry Approach to The Efficient Synthesis of Polyoxometalate-Polymer Hybrids with Well-Defined Structures
作者：MinBiao Hu, Nan Xia, Wei Yu, Chi Ma, Jing Tang, Zhan-Yao Hou, Ping Zheng, Wei Wang
關鍵字：Click Chemistry, Hybrid Polymer, Polyoxometalates
論文來源：期刊
具體來源：Polymer Chemistry
發表時間：2012年
In this study a click chemistry approach was used to synthesize polyoxometalate–polymer hybrids with well-defined structures. The starting materials were a two-azido-containing organosilyl derivative of a Wells-Dawson-type polyoxometalate and a propargyl-terminated poly(ε-caprolactone). The clicking reaction between the azido groups and alkynyl groups was found to be very efficient and the structures of the hybrids were well-defined. This breakthrough will promote a great development in the synthesis of various polyoxometalate–polymer hybrids and broaden their potential application.