Preparation of PE/GO nanocomposites using in situ polymerization over an efficient, thermally stable GO-supported V-based catalyst
writer：He-Xin Zhang,ab Yan-Ming Hu,a Dong-Ho Lee,b Keun-Byoung Yoon*b and Xue-Quan Zhang*a
keywords：graphene, Polyethylene, Ziegler-Natta
source：期刊
specific source：RSC Adv., 2016, 6, 26553
Issue time：2016年
In the present article, an efficient and thermally stable vanadium (V)-based Ziegler–Natta catalyst supported on graphene oxide (GO) was synthesized. The resultant catalyst exhibited highly dispersed active sites along the surface, superior catalytic activity toward ethylene polymerization, and enhanced thermal stability, in contrast to the conventional VOCl3 catalyst. Interestingly, the resultant polyethylene (PE)/GO nanocomposite exhibited a higher thermal stability and better mechanical properties than PE obtained using VOCl3. Transmission electron microscopy reveals graphene homogeneously dispersed within the PE matrix.