[Journal of Materials Science & Technology]Block copolymer functionalized quartz fibers/cyanate ester wave-transparent laminated composites
作者：Jiani Zhang, Zheng Liu, Muyi Han, Junliang Zhang, Yusheng Tang* and Junwei Gu*
關鍵字：透波，氰酸酯，石英
論文來源：期刊
具體來源：Journal of Materials Science & Technology
發表時間：2023年
A block copolymer of PDMS-b-PGMA is synthesized by polymerizing glycidyl methacrylate (GMA) via reversible addition-fragmentation chain transfer (RAFT) polymerization applying a polydimethylsiloxane (PDMS) based macro-RAFT agent, which is then performed to functionalize the quartz fibers (QFs@PDMS-b-PGMA) via a simple coating process. Finally, the QFs@PDMS-b-PGMA/bisphenol A dicyanate ester (BADCy) wave-transparent laminated composites are fabricated by high-temperature molding. Nuclear magnetic resonance (NMR) spectroscopy, Fourier transform infrared (FT-IR) spectroscopy and size exclusion chromatography (SEC) demonstrate the successful preparation of PDMS-b-PGMA with expected structure. When the molar mass and coating amount of PDMS-b-PGMA is respectively 8100 g/mol and 2.0 wt%, QFs@PDMS-b-PGMA/BADCy wave-transparent laminated composites present the optimal mechanical properties and wave-transparent performance. The interlaminar shear strength (ILSS) and flexural strength are 53.6 MPa and 552.0 MPa, respectively. Meanwhile, the dielectric constant and dielectric loss values are 2.61 and 0.0028 at 1 MHz (wave transmittance of 93.8%), showing good stability at different frequencies (102 ~ 106 Hz and 8.4 ~ 12.4 GHz) and temperatures (25 ~ 250oC).