50. [Chemical Engineering Journal] Tough and pH-sensitive hydroxypropyl guar gum/polyacrylamide hybrid double-network hydrogel
writer：Jingjing Zhu, Shuang Guan, Qianqian Hu, Guanghui Gao, Kun Xu, Pixin Wang
keywords：Tough, pH, hydrogels
source：期刊
specific source：Chemical Engineering Journal
Issue time：2017年
Using a facile two-step method, the researchers synthesized a pH-responsive double-network (DN) hydrogel with high strength and toughness, consisting of a B(OH)4? linked hydroxypropyl guar gum (HPG) network and a covalently cross-linked polyacrylamide (PAAm) network. The mechanical strength of HPG/PAAm DN gel was investigated as a function of synthesis conditions, HPG content, sodium borate concentration and soaking time. The resulting DN gel exhibited unique pH-responsive properties and excellent mechanical properties, with a fracture stress of 843 kPa, and an excellent extensibility of 1400% (12?14 times its initial length). The relationship between mechanical property and the synergy of HPG and PAAm networks was discussed systematically. The DN gel possessed self-recovery under small deformation, but displayed self-reinforcement under large deformation.