Facile fabrication of underwater superoleophobic membrane based on polyacrylamide/chitosan hydrogel modified metal mesh for oil–water separation
作者：Yang Zhang, Zheng Cao, Zili Luo, Wenjun Li, Tao Fu, Wang Qiu, Zhirong Lai, Junfeng Cheng, Ha
關鍵字：underwater superleophobic, membrane, hydrogel
論文來源：期刊
具體來源：Journal of Polymer Science
發表時間：2022年
Using chemically etched stainless steel mesh (SSM) as matrix, chitosan (CS) as the hydrophilic component and acrylamide as (AAm) monomer, the underwater superoleophobic membrane (PAAm/CS@SSM) for oil–water separation was prepared by free radical polymerization initiated by ultraviolet light. The composition, morphology, underwater oil contact angle, and structure of PAAm/CS@SSM were characterized by Fourier-transform infrared spectroscopy, x-ray powder diffraction, scanning electron microscopy, and confocal laser scanning microscopy. The underwater oil contact angles of PAAm/CS@SSM could reach 154.5°. When the number of oil–water cycles reached 20 times, the oil–water separation efficiency of PAAm/CS@SSM was larger than 99%. When the oil–water ratio is 1:3, 1:2, 1:1, 2:1, 3:1, the oil–water separation flux of PAAm/CS@SSM was 2096.8, 4457.9, 4735.7, 5395.7, and 3606.9 L·m·?2·h?1, respectively. When oils are n-hexane, petroleum ether, vegetable oil, and liquid paraffin, the oil–water separation efficiency of PAAm/CS@SSM was 99.0%, 97.7%, 97.2%, and 99.3%, respectively. After the wear resistance test, the PAAm/CS@SSM membrane still exhibited underwater super-oleophobicity (>150°).