Organic-inorganic hybrid superhydrophobic surfaces using methyltriethoxysilane and tetraethoxysilane sol-gel derived materials in emulsion
作者：Wen XiuFang,Wang Kun,Pi PiHui,Yang JinXin,Cai ZhiQi,Zhang Lijuan,Qian Yu,Yang, ZhuoRu,Zheng Dafeng
關鍵字：Superhydrophobic surface, Organic-inorganic hybrids, Sol-gel process, MTES/TEOS, Hydrophobic silica
論文來源：期刊
具體來源：APPLIED SURFACE SCIENCE卷: 258 期: 3 頁: 991-998
發表時間：2011年
By applying alkaline-catalyzed co-hydrolysis and copolycondensation reactions of tetraethoxysilane (TEOS) and methyltriethoxysilane (MTES) in organic siloxane modified polyacrylate emulsion (OSPA emulsion), we are able to demonstrate the potential for developing a sol-gel derived organic-inorganic hybrid emulsion for a superhydrophobic surface research. TEOS and MTES derived sol-gel moieties can be designed for a physical roughness and hydrophobic characteristic (Si-CH(3)) of the hybrid superhydrophobic surface, while OSPA emulsion can be endowed for good film-forming property. The effect of formulation parameters on superhydrophobicity and film-forming property was analyzed. The water contact angle (WCA) on the sol-gel derived hybrid film is determined to be 156 degrees, and the contact angle hysteresis is 5 degrees by keeping the mole ratio of TEOS: MTES:C(2)H(5)OH:NH(3)center dot H(2)O:AMP-95 at 1:4:30:10:0.63 and the mass percentage of OSPA emulsion at 25%. The nanoparticle-based silica rough surface is observed as the mole ratio of MTES/TEOS at 4:1. The sol-gel derived organic-inorganic hybrid emulsion shows remarkable film-forming property when the mole ratio of MTES/TEOS reaches or exceeds 4:1. With the primer coating, the performance of superhydrophobic film achieve actual use standard. It reveals that this new procedure is an effective shortcut to obtain a superhydrophobic surface with potential applications.