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鐩?/span>鍏?/span>鐮?/span>絀?/span>鎴?/span>鏋?/span>浠?/span>棰?/span>涓?/span>鈥?/span>Uniform Deposition and Effective Confinement of Lithium in Three-Dimensional Interconnected Microchannels for Stable Lithium Metal Anodes鈥?/span>鍙?/span>琛?/span>鍦?/span>銆?/span>ACS Applied Materials & Interfaces銆?/span>錛?/span>騫?/span>琚?/span>閫?/span>涓?/span>褰?/span>鏈?/span>鐨?/span>琛?/span>鍏?/span>灝?/span>闈?/span>銆?/span>涓?/span>鍗?/span>澶?/span>瀛?/span>寮?/span>鏅?/span>鏅?/span>鍔?/span>鐞?/span>鐮?/span>絀?/span>鍛?/span>涓?/span>璁?/span>鏂?/span>絎?/span>涓浣?/span>鑰?/span>銆?/span>姝?/span>鐮?/span>絀?/span>寰?/span>鍒?/span>鍥?/span>瀹?/span>鑷?/span>鐒?/span>縐?/span>瀛?/span>鍩?/span>閲?/span>鍜?/span>涓?/span>嫻?/span>甯?/span>縐?/span>濮?/span>絳?/span>緇?/span>璐?/span>鐨?/span>璧?/span>鍔?/span>銆?/span>


鍥?/span>1. 鏉?/span>鏂?/span>鐨?/span>鍒?/span>澶?/span>絳?/span>鐣?/span>涓?/span>琛?/span>寰?/span>銆?/span>錛?/span>a錛?/span>HTCNF鍚?/span>鎴?/span>紺?/span>鎰?/span>鍥?/span>錛?/span>錛?/span>b錛?/span>鏉?/span>鏂?/span>鐨?/span>XRD鍥?/span>錛?/span>錛?/span>c錛?/span>HPCNF鐨?/span>SEM鍥?/span>錛?/span> HMCNF-2鐨?/span>錛?/span>d錛?/span>SEM 鍥?/span>錛?/span>錛?/span>e錛?/span>TEM鍥?/span>錛?/span>錛?/span>f錛?/span>g錛?/span>HRTEM鍥?/span>錛?/span>浠?/span>鍙?/span>錛?/span>h錛?/span> C錛?/span>Ti錛?/span>N鍜?/span>O鍏?/span>绱?/span>鍒?/span>甯?/span>鍥?/span>銆?/span>


鍥?/span>2. 閿?/span>褰?/span>鏍?/span>鐨?/span>榪?/span>鐢?/span>浣?/span>瀵?/span>姣?/span>鍥?/span>銆?/span>錛?/span>a錛?/span>Li錛?/span>錛?/span>b錛?/span>HPCNF錛?/span>錛?/span>c錛?/span>HMNCF-2錛?/span>浠?/span>鍙?/span>錛?/span>d錛?/span>榪?/span>鐢?/span>浣?/span>姹?/span>鎬?/span>鍥?/span>銆?/span>


鍥?/span>3. 瀵?/span>縐?/span>鐢?/span>姹?/span>鐨?/span>鐢?/span>鍖?/span>瀛?/span>鎬?/span>鑳?/span>琛?/span>寰?/span>銆?/span>瀵?/span>縐?/span>鐢?/span>姹?/span>鍦?/span>鐢?/span>嫻?/span>瀵?/span>搴?/span>涓?/span>錛?/span>a錛?/span>b錛?/span>1 mA cm?2鍜?/span>錛?/span>c錛?/span>d錛?/span>3 mA cm?2涓?/span>鐨?/span>鏋?/span>鍖?/span>鎯?/span>鍐?/span>鍜?/span>寰?/span>鐜?/span>紼?/span>瀹?/span>鎬?/span>嫻?/span>璇?/span>錛?/span>錛?/span>e錛?/span>瀵?/span>縐?/span>鐢?/span>姹?/span>鍦?/span>鐢?/span>嫻?/span>瀵?/span>搴?/span>涓?/span>1-5 mA cm?2涓?/span>鐨?/span>鍊?/span>鐜?/span>鎬?/span>鑳?/span>嫻?/span>璇?/span>錛?/span>浠?/span>鍙?/span>錛?/span>f錛?/span>搴?/span>浼?/span>鏁?/span>鐜?/span>鐨?/span>瀵?/span>姣?/span>嫻?/span>璇?/span>銆?/span>


鍥?/span>4. 瀵?/span>縐?/span>鐢?/span>姹?/span>涓?/span>鍚?/span>寰?/span>鐜?/span>鍦?/span>鏁?/span>鐨?/span>EIS瀵?/span>姣?/span>鍥?/span>錛?/span>錛?/span>a錛?/span>HTCNF-2錛?/span>錛?/span>b錛?/span>HPCNF銆?/span>HMCNF-2瀵?/span>縐?/span>鐢?/span>姹?/span>寰?/span>鐜?/span>300鍦?/span>鍚?/span>鐨?/span>錛?/span>c-e錛?/span>SEM鍥?/span>錛?/span>錛?/span>f錛?/span>TEM鍥?/span>錛?/span>浠?/span>鍙?/span>錛?/span>g錛?/span>C錛?/span>Ti錛?/span> O錛?/span>N鍜?/span>S鍏?/span>绱?/span>鍒?/span>甯?/span>鍥?/span>銆?/span>


鍥?/span>5. 錛?/span>a錛?/span>HMCNF-2涓?/span>TiO2錛?/span>紕?/span>錛?/span>鐭?/span>澧?/span>-N錛?/span>鍚?/span>鍜?/span>-N鍜?/span>鍚?/span>鍟?/span>-N鍚?/span>闄?/span>涓涓?/span>Li鍘?/span>瀛?/span>鐨?/span>鍚?/span>闄?/span>鑳?/span>銆?/span>錛?/span>b錛?/span>c錛?/span>鍦?/span>0.1 mA h cm?2錛?/span>錛?/span>d錛?/span>e錛?/span>1 mA h cm?2錛?/span>錛?/span>f錛?/span>g錛?/span>3 mA h cm?2錛?/span>鍜?/span>錛?/span>h錛?/span>i錛?/span>5 mA h cm?2鐨?/span>閲?/span>灞?/span>閿?/span>娌?/span>縐?/span>瀹?/span>閲?/span>涓?/span>HMCNF-2涓?/span>浣?/span>鐨?/span>SEM鍥?/span>銆?/span>


鍥?/span>6. 鍦?/span>HMCNF-2涓?/span>Li娌?/span>縐?/span>鐨?/span>妯?/span>鎷?/span>鍥?/span>銆?/span>




鍥?/span>7. HMCNF-2-Li//LFP鍏?/span>鐢?/span>姹?/span>鐨?/span>鐢?/span>鍖?/span>瀛?/span>鎬?/span>鑳?/span>琛?/span>寰?/span>銆?/span>錛?/span>a錛?/span>鍦?/span>0.5 C鐢?/span>嫻?/span>瀵?/span>搴?/span>涓?/span>鐨?/span>闀?/span>寰?/span>鐜?/span>瀵?/span>姣?/span>錛?/span>錛?/span>b錛?/span>鍊?/span>鐜?/span>鎬?/span>鑳?/span>瀵?/span>姣?/span>錛?/span>浠?/span>鍙?/span>鍦?/span>涓?/span>鍚?/span>鐢?/span>嫻?/span>涓?/span>鐨?/span>鐢?/span>鍘?/span>-瀹?/span>閲?/span>鏇?/span>綰?/span>瀵?/span>姣?/span>錛?/span>錛?/span>c錛?/span>0.5 C錛?/span>錛?/span>d錛?/span>1 C錛?/span>錛?/span>e錛?/span>2 C鍜?/span>錛?/span>f錛?/span>5 C銆?/span>


鍘?/strong>鏂?/strong>閾?/strong>鎺?/strong>
https://doi.org/10.1021/acsami.1c09319

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