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 | 濉戞枡 | 姍¤兌 | 綰ょ淮 | 娑傛枡涓庢補(bǔ)澧?/a> | 鑳剁矘鍓?/a> | 澶嶅悎鏉愭枡 | 鐭沖寲 | 鍖栧伐 | 浠櫒浠〃 | 鏂頒駭涓?/a> | 涓撻 | 榪斿洖棣栭〉 |
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| 濉戞枡 | 姍¤兌 | 綰ょ淮 | 娑傛枡涓庢補(bǔ)澧?/a> | 鑳剁矘鍓?/a> | 澶嶅悎鏉愭枡 | 鐭沖寲 | 鍖栧伐 | 浠櫒浠〃 | 鏂頒駭涓?/a> | 涓撻 | 榪斿洖棣栭〉 |
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綰湁鏈哄娓╃７鍏夌敱浜庡叾闀垮鍛戒笖鍏鋒湁杈冨ぇ鐨勬柉鎵樺厠鏂綅縐葷瓑鐗圭偣錛岃繖浣垮緱鍏跺湪鐢熺墿鎴愬儚錛屾暟鎹姞瀵嗛槻浼瓑鏂歸潰鏈夊法澶х殑搴旂敤鍓嶆櫙銆備絾鏄紝鐢變簬瀹ゆ俯紓峰厜瀹規(guī)槗鍙楀埌娓╁害錛屾哀姘旂殑褰卞搷錛屽挨鍏跺湪姘存憾娑蹭腑鏇村鏄撳彈鍒版潅璐ㄧ殑鏀誨嚮鑰屾番鐏傚洜姝わ紝濡備綍鎻愰珮紓峰厜鐨勫彂鍏夋晥鐜囨槸涓欏規(guī)寫鎴樻х殑宸ヤ綔銆?
鍗楀紑澶у鍒樿偛鏁欐巿榪戜袱騫存彁鍑轟簡鈥滀富浣撹瀵煎寮哄浣撶７鍏夊彂鍏夆濈殑鐞嗚錛氬闅忎富鍙樺姪紿滆秺錛圓ngew. Chem. Int. Ed. 2019, 131, 6089-6093.錛夛紝閬塊噸灝辮交闀垮彂鍏夛紙Chem. Sci., 2019, 10, 7773-7778.錛夛紝鍗忓悓絳栫暐涓ょ浉瀹滐紙Angew. Chem. Int. Ed. 2020, 59, 18748-18754.錛夛紝姘翠腑紓峰厜鏉ユ垚鍍忥紙Nat. Commun. 2020,11, 4655.錛夈傝繎鏃ワ紝鍒樿偛鏁欐巿璇鵑緇勫湪銆夾dvanced Materials銆嬫湡鍒婁笂鍙戣〃浜嗛涓?鈥淪upramolecular Pins with Ultralong Efficient Phosphorescence鈥濈殑璁烘枃錛圖OI: 10.1002/adma.202007476錛夈傝鏂囩珷涓紝浣滆呮姤閬撲簡鐢辨ˉ鑱旀捍鑻熀鍚″暥鐩愬拰钁姦[8]鑴茬粍鎴愮殑瓚呭垎瀛愬埆閽堢粍瑁呬綋銆備笌鈥?:2鈥濓紙one host with two guests錛夊拰 鈥滃ご瀵瑰熬鈥濓紙head-to-tail錛変笉鍚岋紝瓚呭垎瀛愬埆閽堢殑閿悎褰㈠紡鏄?:1鈥濓紙one host with one guests錛夊拰 鈥滃ご瀵瑰ご鈥濓紙head-to-head錛夛紝榪欐牱鐨勯敭鍚堝艦寮忓厠鏈嶄簡瀹綋涔嬮棿鐨勯潤鐢墊帓鏂ュ茍涓斾績榪涗簡鍒嗗瓙鍐呯殑鐢?shù)鑽疯浆绉诲Q圛CT, intramolecular charge transfer錛夈傚皢緇勮浣撴幒鍏ュ瘜鏈夌緹鍩虹殑鍩鴻川鍚庯紝紓峰厜鐨勯噺瀛愪駭鐜囧拰瀵垮懡澶уぇ澧炲己銆備綔鑰呰涓洪珮鐨勭７鍏夋晥鐜囨槸鐢變簬楂樺害鏈夋晥鐨勭郴闂寸獪瓚婏紙intersystem crossing錛変互鍙?qiáng)缂撴參鐨勯潪杈悶畡璺儤q佸鑷淬傛湁鏁堢殑緋婚棿紿滆秺涓昏褰掑洜浜庡浣撳垎瀛愮殑鎶樺彔寮曡搗鐨勮姵鍩虹幆鐨勏-蟺鍫嗙Н錛屽垎瀛愬唴鍗ょ礌閿殑褰㈡垚鍜屽垎瀛愬唴鐢?shù)鑽疯浆绉诲Q屾澶栵紝钁姦[8]鑴茬殑鍒氭х┖鑵斾互鍙?qiáng)妗ヨ仈鐨勭兎鍩洪搼謷屽垰鎬у熀浣撴柦鍔犵殑榪愬姩闄愬埗閮藉噺灝戜簡涓夐噸鎬佽兘閲忕殑鎹熷け銆?
鐢變簬鈥滃垎瀛愭姌鍙犫濈殑鏋勫瀷鏋佸ぇ鍦頒績榪涗簡鍒嗗瓙鍐呯數(shù)鑽瘋漿縐伙紝榪欎嬌寰楀浣撳拰緇勮浣撶殑鍚告敹浠ュ強(qiáng)鍙戝厜閮芥湁杈冨ぇ鐨勫樊寮傦紝浣滆呭埄鐢ㄨ繖縐嶅樊寮傞氳繃鏀瑰彉?gòu)葊鍙戞嘗闀夸互鍙?qiáng)涓诲浣撶殑姣斾緥寰楀堫C簡澶氳壊鍙戝厜鏉愭枡銆傛澶栵紝鐢變簬鍚告敹鍜屽彂灝勭殑綰㈢Щ錛岃秴鍒嗗瓙鍒拡琚敤浜庣粏鑳?yōu)闈跺悜鎴愬儚銆?
鍥?. 瓚呭垎瀛愬埆閽堢ず鎰忓浘
鍥?. 涓諱綋-瀹綋閿悎琛屼負(fù)琛ㄥ緛銆傦紙a錛夊浣撱佷富浣撱佺粍瑁呬綋鏍哥姘㈣氨銆傦紙b錛夌粍瑁呬綋楂樺垎杈ㄨ川璋便傦紙c錛夊浣撱佺粍瑁呬綋妯℃嫙鏋勮薄銆?/span>
鍥?. 緇勮浣撴按婧舵恫鍏夎氨琛ㄥ緛銆傦紙a錛夊浣撲腑閫愭笎鍔犲叆钁姦[8]鑴插叾鍚告敹鍏夎氨鐨勫彉鍖栥傦紙b錛夊浣撲腑閫愭笎鍔犲叆钁姦[8]鑴插叾鍏夎嚧鍙戝厜鍏夎氨鐨勫彉鍖栥傦紙c錛夌粍瑁呬綋鍦ㄧ┖姘斾腑浠ュ強(qiáng)鐪熺┖鑴辨皵鍙戝厜寮哄害鍙樺寲銆傦紙d錛夊浣擄細(xì)钁姦[8]鑴叉祿搴︽瘮涓?:0.5鏃舵憾娑插湪涓嶅悓娉㈤暱嬋鍙戠殑鍙戝厜璋卞浘銆?/strong>
鍥?. 緇勮浣撴按婧舵恫鍏夎氨琛ㄥ緛銆傦紙a錛夌粍瑁呬綋鎺烘潅鍦ㄦ護(hù)綰鎬腑鍦ㄥ娓╂潯浠朵笅628nm澶勫鍛姐傦紙b錛夌粍瑁呬綋鎺烘潅鍦ㄦ護(hù)綰鎬腑鍦ㄥ娓╂潯浠朵笅涓嶅悓嬋鍙戞嘗闀匡紙320 nm鑷?20 nm錛夌殑CIE 1931鑹插害鍥俱傦紙c錛夌粍瑁呬綋鍦ㄧ┖姘斾腑浠ュ強(qiáng)鐪熺┖鑴辨皵鍙戝厜寮哄害鍙樺寲銆傦紙d錛夌粍瑁呬綋鎺烘潅鍦ㄦ護(hù)綰鎬腑鍦ㄥ娓╂潯浠跺湪365 nm涓嬬殑浣欒緣鐓х墖銆?/strong>
鍥?. 鍖栧悎鐗?浠ュ強(qiáng)鍙傛瘮鍖栧悎鐗╃殑鍏夎氨鎬ц川錛氬崟鐙浣撲互鍙?qiáng)涓庤懌鑺8]鑴插艦鎴愮殑緇勮浣撶殑绱鍙鍏夊惛鏀惰氨鍥句互鍙?qiáng)鍏夎嚧鍙戝厜璋卞浘銆?/strong>
鍥?. 緇勮浣撳叡鑱氱劍鍥懼儚銆?/span>
鏈枃鎵榪扮殑瓚呭垎瀛愮粍瑁呯瓥鐣ュ叿鏈夋綔鍦ㄧ殑瀹炵敤鎬э紝淇冭繘鐢ㄤ簬鐢熺墿鎴愬儚鍜岄槻浼簲鐢ㄧ殑綰湁鏈虹７鍏夋潗鏂欑殑寮鍙戙?